近20年来,金属有机骨架材料(MOFs)由于出色的性能被广泛应用于空气污染与水污染的防治,对污染物起到有效的控制。UiO-66及其衍生物由于其优异的稳定性以及可调节性被视为一种极具潜力的MOFs材料,通过选择有机配体、官能团、金属离子活化等方法设计孔径、官能度从而赋予UiO-66特殊的化学、物理性质以适应不同场景需求。简单介绍了UiO-66及其衍生物的的调控方法、合成技术及对于挥发性有机物(VOCs)、水污染的处理及其优缺点,并对UiO-66调控、合成的发展方向进行了展望。
In the past 20 years,metal organic framework materials (MOFs) have been widely used in the prevention of air pollution and water pollution due to their excellent performance,and have effectively controlled the pollutants.UiO-66 and its derivatives are regarded as a highly potential MOF material due to their excellent stability and adjustability.By selecting organic ligands,functional groups,metal ion activation and other methods to design pore size and functionality,UiO-66 special chemical and physical properties to meet the needs of different scenarios.The regulation method,synthesis technology,treatment of volatile organic compounds (VOCs) and water pollution,and its advantages and disadvantages of UiO-66 and its derivatives were briefly introduced.The development direction of regulation and synthesis of UiO-66 was prospected.
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基金资助
国家自然科学基金(51574044);江苏省重点研发计划(产业前瞻与共性关键技术)重点项目(BE2018065)